How should I space my cabinet doors when there’s no post between them?

I’m assuming by the way your question is phrased that these will be inset doors, rather than overlay. If this is correct, I would suggest a spacing of around 1/16” at the most. (I like to use a dime to check spacing.) I would strongly suggest initially building the doors to the full size of the opening, and then trimming them back little by little to get that perfect reveal.